A Course in Inorganic Preparations by Henderson W. E. PDF

By Henderson W. E.

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Synthesis of Tetrazoles . . . . . . . . . . . . . . Synthesis of Triazoles . . . . . . . . . . . . . . Dimroth Reaction . . . . . . . . . . . . . . . Synthesis of Triazoles from Cyclic Acyl Ketene Aminals . . . . . Synthesis of Triazoles from Phosphorus Ylides . . . . . . . Thermal 1,3-Dipolar Reactions . . . . . . . . . . . . Cu(I)-Mediated 1,3-Dipolar Reactions . . . . . . . . . . . . . . . . . . .

It was synthesized from tryptamine and (E)-4,5,6-triO-acetyl-2,3-dideoxy-d-erythro-hex-2-enose. Condensation of tryptamine with 1,2-O-cyclohexylidene d-xylo-pentodialdose gave tetra-hydro analogue 85a [143–145]. 6 Six-Membered Heterocycles with Two Hetero Atoms The presence of two hetero atoms in a six-membered ring increased the possibility of the variant heterocycles which are presented in this section. Location of the hetero atoms can be at the 1,2-, 1,3-, or 1,4-positions. Moreover they can be similar or different.

Cu(I)-Mediated 1,3-Dipolar Reactions . . . . . . . . . . . . . . . . . . . . 44 44 47 49 50 50 50 52 52 55 References . . . . . . . . . . . . . . . . . . . . 61 Abstract Glycosylamines and glycosyl azides are valuable and versatile intermediates in carbohydrate chemistry; furthermore they are easily available in a highly stereoselective fashion. Glycosylamines and their derivatives glycosyl enamines and glycosyl imines can be transformed into N-glycosyl heterocycles.

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A Course in Inorganic Preparations by Henderson W. E.


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